Colorless polyimides derived from rigid trifluoromethyl-substituted triphenylenediamines

Abstract

Colorless polyimides (CPIs) have wide applications in flexible photoelectric devices, thanks to their high transparency and heat-resistance. Herein, three rigid aromatic triphenylenediamine monomers containing varied number and position of trifluoromethyl (-CF3) substituents, i.e., c-3FTP, c-6FTP, and s-6FTP, were designed. The corresponding CPI films were fabricated by polycondensation with the commercial 4,4'-(hexafluoroisopropylidene)diphthalic anhydride (6FDA) or 1,2,4,5-cyclohexanetetracarboxylic dianhydride (CHDA). Due to the steric hindrance of –CF3 groups, three diamines all exhibit large torsion angles within 46.1°–87.1° between benzene rings determined via single crystal analysis. The structure-property analysis reveals that –CF3 substitution located on the central phenyl ring facilitates the high glass transition temperature (Tg), while more –CF3 substitutions are beneficial for high optical transparency. Among all the CPIs, the 6FDA/c-6FTP film exhibits the most remarkable balance in thermal, optical, and dielectric properties, including high thermal resistance (Tg = 385 °C, Td5% = 537 °C), excellent optical transparency (λcutoff = 350 nm, T450 = 84.5%, and b* = 1.44), low dielectric nature (Dk = 2.84, Df = 0.0053) at 10 GHz, and high surface hydrophobicity (θ = 100°, WH2O = 0.25%). This systematic study would complement the basic structure-property relationship of aromatic CPIs and inspire rational development of high-performance aromatic CPI materials toward applications in flexible display or 5G technology.