Colorless and high organosoluble polyimides from 2,5-bis(3,4-dicarboxyphenoxy)- t-butylbenzene dianhydride and aromatic bis(ether amine)s bearing pendent trifluoromethyl groups

Abstract

A series of polyimides III a– h characterized by colorlessness, high transparency, high solubility, and good mechanical property, was synthesized from the aromatic dianhydride, 2,5-bis(3,4-dicarboxyphenoxy)- t-butylbenzene dianhydride (I), and various aromatic diamines ( II a– h ) with pendent trifluoromethyl group via polyaddition, chemical imidization, and direct cast films. The III series showed more colorless than the polyimides ( V and VI series) of 2,2-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride (6FDA) contained, the VI series was synthesized from the II with 6FDA. These films III had cut-off wavelengths between 371 and 376 nm, as well as b* value (a yellowness index) ranging from 3.0 to 4.7. In fact, it is so far the most colorless aromatic polyimide in our systematical researches. The III series had inherent viscosity ranging from 0.72 to 1.33 dL/g and showed excellent solubility in a variety of organic solvents. They were soluble in a concentration of 5–10% in the amide polar solvent, ether solvent, and chlorinated solvent. These films showed strength tensile of 97–123 MPa, dielectric constants of 2.78–3.28 (1 MHz), and moisture absorptions of 0.11–0.36 wt%. The glass transition temperature of the III series was recorded at 214–259 °C, the 10% weight loss temperature was over 468 °C, and the residue was more than 47% at 800 °C in nitrogen.