Coloration and Chromatic Sensing Behavior of Electrospun Cellulose Fibers with Curcumin.

Abstract

The effective approach for coloration and chromatic sensing of electrospun cellulose fabrics with a natural colorant, curcumin, is demonstrated. To achieve high surface area, the morphology of fiber was controlled to have rough and porous surface through an electrospinning of a cellulose acetate (CA) solution under optimized electrospinning parameters and solvent system. The resulting CA fibers were treated with a curcumin dye/NaOH ethanol solution, in which deacetylation of the CA fiber and high-quality coloration with curcumin were simultaneously achieved. As a control, a cotton fiber with similar diameter and smooth surface morphology was treated by the same method, resulting in poor coloration quality. The difference can be attributed to high surface area as well as trapping of dye molecules inside of cellulose fiber during deacetylation. Both fibers were further utilized for a chromatic sensing application for specific toxic gases. The incorporated curcumin dye responded to hydrogen chloride and ammonia gases reversibly via keto-enol tautomerism, and, as a consequence, the color was reversibly changed between reddish-brown and yellow colors. The cellulose fiber fabricated by the electrospinning showed ten times higher and two times quicker responsiveness compared to curcumin-colored cotton fiber sample prepared with the same immersion method.