Color-Tuning Mechanism of Electrically Stretchable Photonic Organogels.

Abstract

In contrast to nano‐processed rigid photonic crystals with fixed structures, soft photonic organic hydrogel beads with dielectric nanostructures possess advanced capabilities, such as stimuli‐responsive deformation and photonic wavelength color changes. Recenlty, advanced from well‐investigated mechanochromic method, an electromechanical stress approach is used to demonstrate electrically induced mechanical color shifts in soft organic photonic hydrogel beads. To better understand the electrically stretchable color change functionality in such soft organic photonic hydrogel systems, the electromechanical wavelength‐tuning mechanism is comprehensively investigated in this study. By employing controllable electroactive dielectric elastomeric actuators, the discoloration wavelength‐tuning process of an electrically stretchable photonic organogel is carefully examined. Based on the experimental in‐situ response of electrically stretchable nano‐spherical polystyrene hydrogel beads, the color change mechanism is meticulously analyzed. Further, changes in the nanostructure of the symmetrically and electrically stretchable organogel are analytically investigated through simulations of its hexagonal close‐packed (HCP) lattice model. Detailed photonic wavelength control factors, such as the refractive index of dielectric materials, lattice diffraction, and bead distance in an organogel lattice, are theoretically studied. Herein, the switcing mechanism of electrically stretchable mechanochromic photonic organogels with photonic stopband‐tuning features are suggested for the first time.