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Abstract
Color modulation was first observed for CT-induced chemiluminescent decomposition of a dioxetane bearing a 3-(anthracen-9-yl)-5-hydroxyphenyl induced by a complex of crown ether with potassium tert-butoxide in benzene system. The phenomenon is rationalized by conformational change of a biaryl moiety in the emitter, which is induced by steric interaction of anthryl and a plane of crown ether complex.
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