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Abstract
Synthesis, crystal structure and spectra properties of enantiopure and corresponding racemic Cu(II)-dipyridine amido complexes are reported. The different coordination styles result in the unexpected chiral-unrelated color changes between chiral and racemic complexes. Molecular packing in the crystal of the racemic - 1 . ( R,R ) and ( S,S ) molecules pack alternately with intermolecular Cu–O bond length of 2.451 Å. ► Chiral-unrelated optical properties could be affected by molecular chirality. ► A racemic and corresponding Enantiopure complex showed different color in crystal. ► The color difference came from the different coordination style of Cu.
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