Abstract

Stabilizing an elusive phase: The wurtzite polymorph of the magnetic semiconductor MnSe, which is also the x=1 end member of the widely studied Zn1−xMnxSe solid solution, was synthesized in high yield for the first time as colloidal nanoparticles using a solution chemistry technique at low temperature (see pictures). Nanoparticles of wurtzite-type MnSe have an optical bandgap of approximately 3.5–3.8 eV and show evidence of antiferromagnetic ordering at 64 K.

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