Abstract
When water is added to dilute MeOH solutions of a hydrophilically modified poly(dimethylsiloxane) (HPM-PDMS), molecularly dispersed HPM-PDMS chains associate to form colloidal droplets of the concentrated phase, which are charged spheres of uniform density with the radius of gyration less than 100 nm. Those droplets are remarkably different from those in solutions of HPM-PDMS directly dissolved in MeOH–water mixtures with0.5 and including 0.1 m NaAc, which may contain the coexisting dilute phase.
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