Abstract

In the absence of collisions chromyl chloride (CrO 2Cl 2) shows orange fluorescence when the parent molecule is irradiated by the focused output Time-resolved fluorescence is investigated over the pressure range 5 × 10 −4 to 15 torr. As the pressure is increased, a secondary collision-ind We interpret the collisionless part of the emission to arise from infrared transitions between the high vibrational levels of the ground state and the

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