Abstract

Shift and broadening parameters for doubly excited states of 5d6d, 5d7d, 5d7s, 5d8s and 6p2 configurations in neutral barium atoms are presented. A tunable dye laser pumped by an excimer laser was used to populate the Rydberg states of Ba by two-photon absorption from the 6s2 1S0 ground state. Inert gases Ar, Kr and Xe at 100 mbar pressure were used as perturbing gases. The resulting line shapes were fitted to a Voigt line shape function, from which shift and broadening parameters were inferred.

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