Abstract
IR multiphoton absorption (MPA) and dissociation (MPD) of Si 2F 6 in Ar were investigated. For the 10R (26) line (979.7 cm −1) of the CO 2 laser, the average number of photons absorbed and the MPD yield were obtained for different laser fluences and buffer gas pressures. The fraction of excited molecules was as high as 70%. The MPD probability was found to be heavily suppressed when more than 5 Torr of Ar buffer gas was added, indicating that vibrational deactivation is predominant over MPA increase with pressure.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of Photochemistry & Photobiology, A: Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
