Abstract
Collision-induced absorption spectra of the CsXe system is studied theoretically by SACCI (symmetry adapted cluster configuration-interaction) theory. The origin of the 6S—5D dipole-induced transition is the existence of 5d Σ and 5d Π quasi-molecular states. The quasistatic model is used for calculations of reduced absorption coefficients. The calculated profiles of the collision-induced absorption spectra reproduce well the experimental spectra.
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