Collision-induced absorption byCO2in the far infrared: Analysis of leading-order moments and interpretation of the experiment

Abstract

The diagrammatic theory, developed recently by the authors [Phys. Rev. A 74, 012732 (2006)], is applied to binary collision-induced properties, with emphasis on induced dipole moments. Assuming rototranslational dynamics to be classical and using irreducible spherical tensor formalism, exact analytical formulas are worked out for the two leading order spectral moments of a collision-induced band by two interacting linear molecules. The formulas are applied to the far infrared absorption by ${\text{CO}}_{2}{\text{-CO}}_{2}$, and permit interpretation of the experiment. This study provides evidence of the adequacy of the electrostatic induction mechanism, provided that hitherto missing vibrational terms of static polarizability are considered.