Collision Dynamics of Large Argon Clusters

Abstract

Classical trajectory calculations of collisions between Ar1000 clusters are carried out to investigate the effects of relative velocity and impact parameter on energy transfer and dynamical behavior. In the velocity range 100−1000 m/s, we conclude that the outcome of the collisions can be classified into a few characteristic scattering channels. We observe coalescence, stretching separation, and shattering collisions, and each collision process dominates within distinguishable parameter ranges. A major part of the available energy ends up in vibrational degrees of freedom, and internally hot systems cool by evaporation as well as more severe fragmentation for high-energy collisions. High rotational excitation is observed for large impact parameter values, and the maximum rotational energy of the collision complex is concluded to mainly determine whether a collision will result in coalescence or stretching separation. The results are related to experimental data for collisions between large liquid droplets, and we conclude that argon clusters in the nanometer range partly resemble the larger systems. The boundary between coalescence and stretching separation is surprisingly well predicted by macroscopic models.