Collective colloid diffusion under soft two-dimensional confinement.

Abstract

This work presents a numerical and theoretical investigation of the collective dynamics of colloids in an unbounded solution but trapped in a harmonic potential. Under strict two-dimensional confinement (infinitely stiff trap) the collective colloidal diffusion is enhanced and diverges at zero wave number (like k^{-1}), due to the hydrodynamic propagation of the confining force across the layer. The analytic solution for the collective diffusion of colloids under a Gaussian trap of width δ still shows enhanced diffusion for large wavelengths kδ<1, while a gradual transition to normal diffusion for kδ>1. At intermediate and short wavelengths, we illustrate to what extent the hydrodynamic enhancement of diffusion is masked by the conservative forces between colloids. At very large wavelengths, the collective diffusion becomes faster than the solvent momentum transport and a transition from Stokesian dynamics to inertial dynamics takes place. Using our inertial coupling method code (resolving fluid inertia), we study this transition by performing simulations at small Schmidt number. Simulations confirm theoretical predictions for the k→0 limit [Phys. Rev. E 90, 062314 (2014)PLEEE81539-375510.1103/PhysRevE.90.062314] showing negative density-density time correlations. However, at finite k simulations show deviations from the theory.