Collapse of polyelectrolyte brushes: Scaling theory and simulations

Abstract

We investigate polyelectrolyte brushes using both scaling arguments and molecular dynamics simulations. As a main result, we find a novel collapsed brush phase. In this phase, the height of the brush results from a competition between steric repulsion between ions and monomers and an attractive force due to electrostatic correlations. As a result, the monomer density inside the brush is independent of the grafting density and the polymerization index. For small ionic and monomer radii (or for large Bjerrum length) the brush undergoes a first-order phase transition from the osmotic into the collapsed state.