Cold welding of gold nanoparticles on mica substrate: Self-adjustment and enhanced diffusion.

Song-Hyun Cha,Kyeounghak Kim,Youmie Park,Jeong Woo Han,Seonho Cho,Hyun-Seok Kim,Hong-Lae Jang

doi:10.1038/srep32951

Song-Hyun Cha, Kyeounghak Kim + Show 5 more

Open Access

https://doi.org/10.1038/srep32951

Copy DOI

Abstract

From the images of HR-TEM, FE-SEM, and AFM, the cold welding of gold nanoparticles (AuNPs) on a mica substrate is observed. The cold-welded gold nanoparticles of 25 nm diameters are found on the mica substrate in AFM measurement whereas the size of cold welding is limited to 10 nm for nanowires and 2~3 nm for nanofilms. Contrary to the nanowires requiring pressure, the AuNPs are able to rotate freely due to the attractive forces from the mica substrate and thus the cold welding goes along by adjusting lattice structures. The gold nanoparticles on the mica substrate are numerically modeled and whose physical characteristics are obtained by the molecular dynamic simulations of LAMMPS. The potential and kinetic energies of AuNPs on the mica substrate provide sufficient energy to overcome the diffusion barrier of gold atoms. After the cold welding, the regularity of lattice structure is maintained since the rotation of AuNPs is allowed due to the presence of mica substrate. It turns out that the growth of AuNPs can be controlled arbitrarily and the welded region is nearly perfect and provides the same crystal orientation and strength as the rest of the nanostructures.

Highlights

It is reported that the cold welding of gold nanocrystals bonding in solution can occur in the pathway of defect-free bonding if their lattices aligned to within a critical angle[7]
It is well-known that there is a strong attractive force between gold atoms and silicate[8], which leads to the conjecture that something has happened in the sample on the mica substrate for the AFM scan
The details of green synthesis is found in the method section at the end of this paper

Summary

Introduction

Despite extensive work regarding the interactions between nanoparticles, the effect of interaction with substrate on the cold welding is rarely found in literature. Regarding the physics in the cold-welding of nanoscale materials, the following is experimentally known in the literature so far;. (2) Nanowire: Single-crystalline gold nanowires with diameters between 3 and 10 nm can be cold-welded under the conditions of mechanical contact and low applied pressures[9]. The cold-welded AuNPs of 25 nm diameters are found on the mica substrate. The initiation of cold welding requires the following conditions; a high applied load, and an atomically clean, flat, and ductile surface in an ultrahigh-vacuum environment[8]. The cold welding can occur on a substrate since there are so-called ‘self-adjustment’ that matches crystalline orientations, requiring little external forces. The high quality of the cold welding is attributed to the followings[2]:

Methods

Results

Conclusion