Coke deposition and run length in industrial naphtha thermal cracking furnaces via a quasi‐steady state coupled CFD model

Abstract

AbstractMathematical modelling of the thickness of the coke layer growing over months in millisecond cracking reactors is a dilemma in computational fluid dynamics (CFD) simulation. To address the time scale issue, a quasi‐steady state (QSS) approach was employed through a comprehensive coupled reactor/firebox CFD model in the current study. The model was applied to predict the time‐dependent behaviour of coke deposition and to determine the appropriate operating conditions for maximum olefin yields over an industrial furnace run length. A novel algorithm was designed to overcome the complexity of QSS simulation of the CFD model, which is a combination of reactive turbulence flow, combustion, and radiation models. The furnace parameters were studied as a function of two variables: the dilution steam‐to‐feed ratio and the liberated heat by the burners. The results indicated that the run length can be extended by up to 20% while retaining the main product yields. This study offers practical suggestions to maximize the run length in the operation.