Coherent Electronic Energy Transfer and Organic Photovoltaics

Abstract

One of the most surprising and significant advances in the study of the photosynthetic light-harvesting process is the discovery that the electronic energy transfer (ET) might involve long-lived electronic coherences, also at physiologically relevant conditions. This means that the transfer of energy among different chromophores does not follow the expected classical incoherent hopping mechanism, but that quantum-mechanical laws can steer the migration of energy. The implications of such quantum transport regime, although currently under debate, might have a tremendous impact in our way to think about natural and artificial light-harvesting and suggest new directions for the development of artificial devices for the efficient capture and re-use of solar energy. Central to these discoveries has been the development of new ultrafast spectroscopic techniques, in particular two-dimensional electronic spectroscopy, which is now the primary tool to obtain clear and definitive experimental proof of such effects.