Abstract

The motion of an exciton in a translationally invariant exciton-phonon system is considered within the frame of the generalized Fulton-Gouterman (FG) transformation, which diagonalizes the coupled exciton-phonon Hamiltonian in the excitonic subspace and yields a set of exact equations for the purely oscillatory FG wave functions. An exact expression for the second moment of the local excitonic occupation numbers is presented in terms of the FG wave functions, for which two different sets of displaced phonon states are discussed. A numerical computation of the second moment characterizes the exciton motion as a coherent process. This result is also found in an improved calculation which is based on the application of the Goldberger-Adams relation. \textcopyright{} 1996 The American Physical Society.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.