Abstract

We present here, the effect of microstructure on the magnetic, electrical and thermal properties of (V0.60Ti0.40)-Gd alloys. Gadolinium is found to be immiscible in V0.60Ti0.40 alloys where it precipitates with size <1.2μm. These precipitates enhance the grain boundary density. The (V0.60Ti0.40)-Gd alloys become ferromagnetic below Tmc = 295 K with an increase in the superconducting transition temperature (Tsc). Though the disorder increases with increasing Gd content, the electronic thermal conductivity (κe(H=0)) reduces by at most 15% which is in contrast with the 80% decrease of the phononic thermal conductivity (κl(H=0)). Our analysis suggests that the magnetic moments of the Gd precipitates polarize the conduction electrons along and around the grain boundaries leading to increase in the mean free path of the electrons. The partial suppression of spin fluctuations in the (V0.60Ti0.40)-Gd alloy by the conduction electron polarization enhances the Tsc.

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