Abstract
We assess currently available experimental data of the diameter of the coexistence curve for the gas–liquid phase transition of pure fluids. Various approaches, including the direct evaluation of dielectric-constant data and the analysis of calorimetric experiments, are found to support a leading |T-Tc|2β singular term in the diameter, with β≅0.326 and Tc the critical temperature. This is consistent with the predictions from “complete scaling” formulation of asymmetric fluid criticality.
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