Abstract
A quantitative electrochemical comparative study is reported which demonstrates that Costa's B 12 model is a closer electrochemical mimic of B 12 than is the widely used cobaloxime model. Also reported are conditions allowing chemically reversible cyclic voltammetry of cobalt-alkyls of Costa’s B 12 model and the surprising effect of axial base concentration upon the apparent cobaltcarbon bond stability subsequent to electrochemical reduction.
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