Abstract
The coefficient of self-diffusion D has been measured in oxygen-free samples of CH 3OH, CHCl 3, CH 3I, and CHBr 3 using pulsed NMR techniques. The results show that D is temperature dependent and logarithmic in 1 T for each liquid. The experimental values are in excellent agreement with the modified Stokes-Einstein relation, which includes the microviscosity factor for translational motion introduced by Gierer and Wirtz. The significant structure theory of liquids, developed by Eyring and Ree, also gives reasonable agreement with the experimental data.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
