Co-effect of bis(cyclohexanone) oxalyldihydrazone and copper(II) ion on the corrosion of cold rolled steel in 0.5 M hydrochloric acid solution

Abstract

Effects of bis(cyclohexanone) oxalyldihydrazone (BCO) and copper(II) ion (Cu2+) on the corrosion of cold rolled steel (CRS) in 0.5 M hydrochloric acid (HCl) solution were investigated using Tafel polarization curve and electrochemical impedance spectroscopy (EIS) at 20 °C. Results elucidate that the inhibition efficiency increases with increase in BCO concentration, and the addition of 10−5 M Cu2+ significantly enhances the inhibition efficiency of BCO. Polarization curve results elucidate that the single BCO acts as a mixed-type inhibitor while the combination of Cu2+ and BCO acts as cathodic inhibitor. Ultraviolet and visible spectrophotometer (UV–Vis) results show that BCO molecules do not interact with Cu2+ and Fe2+ in 0.5 M HCl solution. Atomic force microscope (AFM) result indicates that a protective layer forms on CRS surface after immersion in 0.5 M HCl containing BCO in the absence and presence of Cu2+. The adsorption of BCO is found to follow the Langmuir adsorption isotherm in the presence and absence of Cu2+. The mechanism of typically chemical adsorption is proposed via the value of free energy of adsorption (ΔG) in the presence of BCO and Cu2+.