Coconut Shell Carbon Preparation for Rhodamine B Adsorption and Mechanism Study

Abstract

Phosphoric acid is used as a chemical activator to prepare coconut shell carbon (PCSC), and for investigating rhodamine B (RhB) adsorption performance. The optimal conditions for the preparation of PCSC (calcined temperature, phosphoric acid concentration), and the influence of adsorption conditions (concentration, pH, etc.) on RhB and the recovery performance of optimal carbon are investigated. Experimental results show that when the amount of PCSC (600 °C, 2 h) is 0.2 g, the initial RhB concentration is 10 mg/L, pH = 6, and the adsorption time is 30 min, it can have 95.84% RhB adsorption efficiency. Liquid ultraviolet spectroscopy also supports this adsorption performance. Characterization data showed that hydroxyl and ester groups, aromatic structures, and PO43− existed on the surface of PCSC, and the amount decreased with increasing calcined temperature. PCSC has a BET (N2) surface area of 408.59 m2/g and has a micropore distribution, EDS-detected P content is 3.91%. SEM showed that the PCSC formed micropores which could better adsorb RhB. The kinetic and thermodynamic analysis of the adsorption of RhB by PCSC showed that the adsorption process was in accord with quasi-secondary kinetic equations and ΔGθ was between −1.65 and −18.75 kJ/mol. The adsorption was a physical adsorption and a spontaneous endothermic reaction, and the obtained PCSC sorption isotherms were classified as Langmuir-type. The RhB adsorption mechanism on PCSC includes pore diffusion, hydrogen bonding, and π−π conjugation. The PCSC prepared by H3PO4 modification has superior adsorption and recycling performance for RhB, providing a reference for the preparation of other biomass carbon materials for the treatment of dye wastewater.