Abstract
This chapter reviews the literature on solid-state cobalt-59 (59Co) nuclear magnetic resonance (NMR) so as to complement the existing excellent reviews on solution-state work. A brief account of the recent progress in chemical shift interpretation and relaxation studies is presented, covering the relevant solution-state studies published in the 1990s, in which particular attention is given to controversial results. The chapter also summarizes the advances in the theoretical calculations of 59Co NMR parameters. The focus is on what has been done for 59Co rather than the “technical details” of the treatments. As very little has been reported for spin-spin coupling constants involving 59Co nucleus, the solid-state data compilation was done only for chemical shifts and quadrupole coupling constants. The future trend will be to combine different strategies of solidstate and/or solution-state NMR to provide a unified description of the systems under investigation. In particular, it is anticipated that theoretical calculation will provide a new dimension in 59Co NMR spectroscopy, enabling its application to more complicated systems.
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