Abstract

A new method for the determination of nitrite was established based on cobalt monoxide (CoO) nanoparticles modified glassy carbon electrode (CS-CoO/GCE). In 0.15mol/L pH 4.0 HAc-NaAc, the CS-CoO/GCE showed a remarkable catalytic and enhancement effect on oxidation of the nitrite. A linear dynamic range of 8.0×10-7 to 6.0×10-3 mol/L (R=0.997) with a detection limit of 1.0×10-7 mol/L was obtained. The electrochemical mechanism was been obtained. This method has been used to determine the content of nitrite in real samples.

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