Cobalt molybdate nanoflowers decorated bio-waste derived porous activated carbon nanocomposite: A high performance electrode material for supercapacitors

Abstract

In this work, we report a supercapacitor electrode material based on nano-flower like cobalt molybdate decorated on porous activated carbon derived from waste onion peels (β-CoMoO4-POAC). The obtained POAC exhibits highly porous structure and after the hydrothermal treatment with salts of cobalt and molybdenum, we observed a uniform distribution of β-cobalt molybdate (β-CoMoO4) as nano-flowers on the surface of POAC. The chemical composition, morphology and porosity of the materials were thoroughly analyzed using field emission scanning electron microscopy, X-ray photoelectron spectroscopy, X-ray diffraction, infrared spectroscopy and Brunauer–Emmet–Teller surface area measurement. Due to its flower like and highly porous morphology, β-CoMoO4@POAC exhibits a high specific capacitance of 1110.72 F/g at a current density of 1 mA/cm2 with superior cyclic retention of 96.03% after 2000 cycles. The best electrochemical performance exhibited by β-CoMoO4@POAC is mainly due to its high surface area and porous nature of the material which assists in active transport of ions. This study reveals the exceptional electrochemical properties of β-CoMoO4@POAC which could be considered as a potential material for advanced energy storage devices.