Coating evaluation and validation of accelerated test conditions using an in-situ corrosion sensor

Abstract

An in-situ corrosion sensor was used to obtain electrochemical impedance spectroscopy (EIS) measurements on coated panels under a variety of accelerated laboratory test conditions as well as ambient exposure at a Florida beach. Three studies are reported. The first compared the sensor (EIS) measurements taken in a salt fog chamber to those obtained using a clamp-on cell and the conventional remote electrode/immersion approach. For coatings with minimal edge defects, the two methods gave equivalent results. For coatings with edge defects, the sensor was able to detect the defects provided the surface was wet, as in the salt fog chamber. In contrast, the conventional approach was unable to detect defects unless they were within the confines of the clamp-on cell. In the second case, sensor measurements were used to compare coating degradation during salt fog, a cyclic corrosion test, humidity, and immersion to that occurring at a Florida beach. The cyclic corrosion test showed an excellent correlation with beach exposure while the salt fog and other test showed very little correlation, suggesting that the cyclic test is more valid for discriminating coating performance for seacoast exposure. The sensor also indicated that the test could be short-ened by up to 40% without significantly reducing the validity of the test. In the final example, a series of primers and appliques were evaluated using the cyclic corrosion test. The sensor EIS results allowed a discrimination between the materials sets even though there was little or no visual difference between the specimens.