Abstract
Polymers containing covalently attached 18-crown-6 or 2.2.2 cryptand units were incorporated into plasticized PVC membranes and the composite membranes were examined as potassium ion sensor elements. Ionophores were linked to carboxy-PVC and to poly(acrylic acid) via amide linkages to an alkyl spacer unit. Coated-wire electrodes (CWEs) from the immobilized ionophores gave acceptable responses, but conventional ion-selective membrane electrodes (ISEs) prepared by solvent casting were inactive. Dip-cast membranes did give active ISEs. Potassium electrode performance was independent of the loading of the ionophore within the acrylate support polymer, but depended upon the spacer length. Ion selectivity varied with the ionophore loading within the support polymer. Selectivity is a composite of the ionophore selectivity and ion-exchange interactions with the acrylate backbone, giving selectivities akin to carboxylate substituted crown ethers, notably enhanced monovalent/divalent ion discrimination relative to the ionophore in solution. Polymer immobilization extended the lifetime of active electrodes.
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