Abstract
Both oxidative and reductive enzymes can be utilized to enhance coal solubilization in aqueous and organic media. Aerobic solubilization was carried out with oxidases in a relatively polar medium, whereas solubilization in an anaerobic environment was conducted with reducing enzymes (dehydrogenase or hydrogenase) in aqueous and both polar and nonpolar organic media in the presence of hydrogen or a hydrogen donor. Solubilization of some enzymes in organic liquids was enhanced by complexation with polyethylene glycol. Enzyme concentration of 1–20 mg/mL was used, and most of the reactions occurred during the first 4 h, with up to 85% of the coal solubilized. There was some evidence of coal product inhibition and enzyme deactivation at higher temperatures.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.