Coagulative removal of microplastics from aqueous matrices: Recent progresses and future perspectives

Abstract

Coagulation-flocculation-sedimentation (CFS) system has been identified as one of the favored treatment technique in water/wastewater treatment systems and hence, it is crucial to comprehend the efficacy of different coagulants used in removing microplastics (MPs) from aqueous matrices. Henceforth, this study critically reviews the recent progress and efficacy of different coagulants used to date for MPs removal. This includes laboratory and field-scale studies on inorganic and organic coagulants, as well as laboratory-scale studies on natural coagulants. Inorganic and organic coagulants have varying MPs removal efficiencies such as: Fe/Al-salts (30 %–95 %), alum (99 %), and poly aluminum chloride (13 %–97 %), magnesium hydroxide (84 %), polyamine (99 %), organosilanes (>95 %), and polyacrylamide (85 %–98 %). Moreover, studies have highlighted the use of natural coagulants, such as chitosan, protein amyloid fibrils, and starch has shown promising results in MPs removal with sevral advantages over traditional coagulants. These natural coagulants have demonstrated high MPs removal efficiencies with chitosan-tannic acid (95 %), protein amyloid fibrils (98 %), and starch (>90 %). Moreover, the MPs removal efficiencies of natural coagulants are compared and their predominant removal mechanisms are determined. Plant-based natural coagulants can potentially remove MPs through mechanisms such as polymer bridging and charge neutralization. Further, a systematic analysis on the effect of operational parameters highlights that the pH affects particle surface charge and coagulation efficiency, while mixing speed affects particle aggregation and sedimentation. Also, the optimal mixing speed for effective MPs removal depends on coagulant type and concentration, water composition, and MPs characteristics. Moreover, this work highlights the advantages and limitations of using different coagulants for MPs removal and discusses the challenges and future prospects in scaling up these laboratory studies for real-time applications.