Abstract

Red mud is a waste stream the Bayer process for alumina production. This paper deals mainly with the influence of pH on the coagulation and dispersion of red mud suspensions. For the purpose of understanding the coagulation and dispersion phenomena of dilute red mud suspensions, the relationship between zeta potential of red mud and pH is measured, and the phenomena in the case of basic suspensions are analyzed by using the experimental data of zeta potential and the DLVO theory. It is shown that the theory agrees fairly well with the experimental results. Furthermore, measurements of the specific volume of sediment, the zeta potential, the mass fraction of less than 2 μm in red mud and the apparent viscosity of some kinds of slurries, show that in order to entirely disperse red mud suspensions, the addition of a dispersing agent to the suspensions is necessary.

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