Abstract
The coadsorption of oxygen, bromine and sodium with water on Cu(110) has been studied using ultraviolet photoelectron spectroseopy, thermal desorption spectroscopy, measurements of work function changes and low energy electron diffraction. Compared to the clean surface, these ionic coadsorbates give rise to striking modifications of the adsorption behaviour of water, with a pronounced dependence on submonolayer coadsorbate coverage. Possible electrochemical implications of these results, in particular with regards to the electric double layer formed at the metal-electrolyte interface, are briefly discussed.
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