Abstract
The first versatile gas-controlled polymerization switch based on reversible absorption of CO2 by organic amidine was developed. The amidine/alcohol system, which originally belonged to CO2 binding organic liquids, served as an efficient CO2-responsive catalyst/initiator system for lactide polymerization. Chemoselective block copolymerization between polylactide and polycarbonate was further explored by opposite gas-controlled amidine and another CrIII catalyst, where an immortal strategy was developed for conjugated alternation of inverse polymerizations on different active species and permits many potential applications.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.