CO2 Adsorption Behavior of Activated Coal Char Modified with Tetraethylenepentamine

Abstract

The climate deterioration problem mainly caused by excessive CO2 emission from coal-fired power plants has led to heightened concerns, and the reduction of the separation cost of CO2 is essential to realize the industrial application of adsorption technology. The activated char was obtained by passing water vapor through a reactor while pyrolyzing coal at 650 °C, which was further pore-expanded using HCl. Then, the pore-expanded activated char was impregnated with tetraethylenepentamine (TEPA) for the preparation of amine-modified solid sorbents for CO2 capture. The effects of the HCl concentration, coal type, adsorption temperature, and activation time of water vapor on CO2 adsorption were investigated in a fixed-bed reactor, and the regenerability, kinetics, and deactivation rate during the adsorption process for sorbents were also studied. The saturated adsorption capacity of 3.38 mmol/g was obtained for 10 wt % TEPA-modified Ordos coal activated char (PE6-E120-TEPA10%) at 60 °C. After 10 adsorption–de...