Co-partial oxidation of acetic acid, methanol, and ethanol in an integrated porous media with efficient heat recirculation: Green hydrogen production and its expansion method

Abstract

Green energy from biomass contributed to substituting the traditional fossil fuels and environmental protection. To explore the hydrogen production from bioethanol with the industrial by-products, a porous media burner integrated with a heat-recirculating tube was designed to realize the efficient vaporization of ethanol. Then the partial oxidation characteristics of ethanol were investigated with the acetic acid and methanol addition at different operating conditions. The results indicated that the acetic acid and methanol addition inhibited hydrogen production but promoted methane production. Compared with pure ethanol, the heating values of syngas were decreased by 3.41 and 0.64 MJ/Nm3 with the acetic acid or methanol content of 20%. The highest yields of hydrogen and carbon monoxide were achieved at 43.94% and 66.45% respectively when the ratio of acetic acid content to methanol was 5:15. Nevertheless, blended fuels achieved more syngas production at higher equivalence ratios and velocities. The hydrogen concentration of the blended fuel reached the maximum of 21%, exceeding that of pure ethanol by 1.6% when the velocity was 22 cm/s. The corresponding results provided a theoretical reference for the industrial application of bioethanol.