Abstract

Co(III)DMG, [ Co(III)DMG is CO(DH) (DH2)Cl2, where DH is monoanion of dimethylglyoxime ], complex catalyses the allylation of 1, 3-dicarbonyl compounds with allyl alcohols in good yields. These reactions are highly regioselective as compared to the corresponding Co(II) catalyzed transformation using allyl acetates.

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