Co(II) Adsorption in Aqueous Media by a Synthetic Fe–Mn Binary Oxide Adsorbent

Abstract

Co(II) adsorption on high-purity amorphous Fe–Mn binary oxide adsorbent was investigated. The Co(II) adsorption behavior of this synthetic material was studied and discussed as a function of contact time, pH and initial concentration. The Langmuir and Freundlich isotherm models were applied to fit the Co(II) adsorption data on Fe–Mn binary oxide with mesoporous particles of irregular surface morphology and a specific surface area of 201.8 m2 g−1 with a maximum capacity of 32.25 mg g−1. Various kinetic models applied to the adsorption rate data of the Co(II) ion were evaluated. The results show that the pseudo-second order and the intra-particle mass transfer diffusion models correlated best with the experimental rate data. The adsorption activation energy was found to be 9.07 kJ mol−1 indicating that it corresponds to a physical adsorption. The evaluated thermodynamics parameters of the adsorption values indicated the endothermic and spontaneous nature of the adsorption. The results obtained confirmed that Fe–Mn binary oxide had the potential to be utilized as a low-cost and relatively effective adsorbent for Co(II) removal from wastewater.