Co-hydrolysis of TEOS and DDS to obtain a modified hydrophobic SiO2 insulation layer for FeSiBC amorphous magnetic powder core with low energy loss

Abstract

The hysteresis effect and eddy currents caused by alternating magnetic fields greatly impede the improvement of the working efficiency and performance stability of soft magnetic powder cores. In this work, modified hydrophobic SiO2 nanoparticles were prepared by tetraethyl orthosilicate (TEOS) and dimethyl-diethoxy-silane (DDS) as co-precursors through sol–gel methods. The effect of different proportions of DDS and TEOS on the amorphous magnetic powder cores performance was studied. It was demonstrated that the insulation layer in DDS and TEOS co-precursors hydrolyzed composite powders exhibited more uniform distribution compared with TEOS hydrolyzed alone counterpart. The introduction of methyl groups reduced the accumulation of hydrolysis intermediates on the surface of FeSiBC powders. Furthermore, the addition of DDS reduced eddy current loss significantly with a low hysteresis loss. The total energy loss of the DDS and TEOS co-hydrolysis powder core were reduced by 16.1 % and 7.7 % at 1 MHz, 0.05 T compared to the uncoated powder core and the TEOS hydrolysis alone counterpart, respectively. The presented results provide insights into improving the application range and energy utilization efficiency for the magnetic powder cores.