Abstract
IRAS studies of CO adsorption on the Au(110)−(1 × 2) surface were performed as a function of CO pressure and sample temperature. It was found that with increasing coverage, the CO IRAS absorption shifts red from 2118 to 2108 cm-1. Clausius−Clapeyron data analysis yielded a heat of CO adsorption (−ΔHads) of 10.9 kcal/mol at low coverages and 7.8 kcal/mol at coverages greater than 19%.
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