Abstract

This paper describes a series of experiments conducted with natural gas in air and in mixtures of oxygen and recycled flue gas, termed O 2/CO 2 recycle combustion. The objective is to enrich the flue gas with CO 2 to facilitate its capture and sequestration. Detailed measurements of gas composition, flame temperature and heat flux profiles were taken inside CANMET's 0.3 MWth down-fired vertical combustor fitted with a proprietary pilot scale burner. Flue gas composition was continuously monitored. The effects of burner operation, including swirling of secondary stream and air staging, on flame characteristics and NO x emissions were also studied. The results of this work indicate that oxy–gas combustion techniques based on O 2/CO 2 combustion with flue gas recycle offer excellent potential for retrofit to conventional boilers for CO 2 emission abatement. Other benefits of the technology include considerable reduction and even elimination of NO x emissions, improved plant efficiency due to lower gas volume and better operational flexibility.

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