Abstract

Several C-nitro compounds were demonstrated to nitrosate morpholine, a secondary amine, to form N-nitrosomorpholine (NMOR). These C-nitro compounds responded to thermal energy analyzer (TEA); however, there was no correlation between the nitrosation rate and the relative TEA molar response of the C-nitro compounds. Alkyl and aromatic C-nitro compounds bearing electron-withdrawing groups such as NO 2, Br, Cl and F were active nitrosating agents. On the other hand, C-nitro compounds without such electron-withdrawing groups did not nitrosate morpholine.

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