Abstract
The electronic structures of TiCl 4 and TiCl 6 2− are investigated on the basis of CNDO procedure. Average energies of electronic configurations of atoms are used to evaluate local core hamiltonian U μμ and the Slater exponents which reproduce one-center repulsion integrals γ μν assuming that they arise from spherically symmetric charge distributions of the valence atomic orbitals. Quite good agreement has been obtained in the interpretation of the experimental data as the photoelectron spectrum of TiCl 4 and the optical spectra of the examined systems.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
