Abstract
The catalytic activity of dimeric [Pd{C6H2(CH2CH2NH2)–(OMe)2,2,3}(m-Br)]2 complex was investigated in the synthesis of benzonitriles under microwave irradiation conditions. The substituted benzonitriles were produced from various aryl halides in excellent yields and short reaction times using a catalytic amount of this complex as efficient, stable and air- and moisture-tolerant catalyst, and K4[Fe(CN)6] as a green cyanide source in DMF at 130 °C.
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