Abstract

AbstractThe CM carbonaceous chondrites provide unique insights into the composition of the protoplanetary disk, and the accretion and geological history of their parent C‐complex asteroid(s). Of the hundreds of CMs that are available for study, the majority are finds and so may have been compromised by terrestrial weathering. Nineteen falls have been recovered between 1838 and 2020, and there is a hint of two temporal clusters: 1930–1942 and 2009–2020. Falls are considered preferable to finds to study because they should be near pristine, and here this assumption is tested by investigating their susceptibility to alteration before recovery and during curation. CMs falling on the land surface are prone to contamination by organic compounds from soil and vegetation. Where exposed to liquid water prior to collection, minerals including oldhamite can be dissolved and most fluid mobile elements leached. Within days of recovery, CMs adsorb water from the atmosphere and are commonly contaminated by airborne hydrocarbons. Interaction with atmospheric water and oxygen during curation over year to decadal timescales can produce Fe‐oxyhydroxides from Fe,Ni metal and gypsum from indigenous gypsum and oldhamite. Relationships between the petrologic (sub)types of pre‐1970 falls and their terrestrial age could be due to extensive but cryptic alteration during curation, but are more likely a sampling bias. The terrestrial history of a CM fall, including circumstances of its collection and conditions of its curation, must be taken into account before it is used to infer processes on C‐complex parent bodies such as Ryugu and Bennu.

Highlights

  • Carbonaceous chondrite meteorites sample primitive bodies, most probably C-complex asteroids (Burbine 2017; Bates et al 2020)

  • This list does not include Diepenveen (27/10/1873, Netherlands/52°N, 68.4 g) that is classified as CM2-an in the Meteoritical Bulletin database, and Sutter’s Mill (22/04/2012, USA/38° N, 993 g) that is classified as C (Ruzika et al 2014), described as a CM2 breccia (Jenniskens et al 2012; Zolensky et al 2014). aData from the Meteoritical Bulletin. bDay/month/year. cMineralogic Alteration Index (Browning et al 1996). dAs defined by Rubin et al (2007). eData from Lentfort et al (2020)

  • The contact of carbonaceous chondrite falls with liquid water prior to recovery can have a significant impact on their mineralogy and composition, as highlighted by Tagish Lake and Sutter’s Mill

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Summary

CM carbonaceous chondrite falls and their terrestrial alteration

Abstract–The CM carbonaceous chondrites provide unique insights into the composition of the protoplanetary disk, and the accretion and geological history of their parent C-complex asteroid(s). Of the hundreds of CMs that are available for study, the majority are finds and so may have been compromised by terrestrial weathering. Falls are considered preferable to finds to study because they should be near pristine, and here this assumption is tested by investigating their susceptibility to alteration before recovery and during curation. CMs adsorb water from the atmosphere and are commonly contaminated by airborne hydrocarbons. Interaction with atmospheric water and oxygen during curation over year to decadal timescales can produce Feoxyhydroxides from Fe,Ni metal and gypsum from indigenous gypsum and oldhamite. The terrestrial history of a CM fall, including circumstances of its collection and conditions of its curation, must be taken into account before it is used to infer processes on C-complex parent bodies such as Ryugu and Bennu

INTRODUCTION
COMPOSITION OF THE CM GROUP
Santa Cruz
Identifying Terrestrial Alteration
TERRESTRIAL WEATHERING OF CM FINDS
EVIDENCE FOR TERRESTRIAL ALTERATION OF CM FALLS
Organic Contamination
Leaching and Dissolution by Liquid Water Before Recovery
Hydrolysis and Oxidation from Atmospheric Exposure
ALTERATION CHRONOLOGY OF CM FALLS
IMPLICATIONS FOR COLLECTION AND CURATION
Findings
SUMMARY AND CONCLUSIONS
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