Abstract
New cluster gold compounds with 1,2-bis((diphenylphosphino) ethane (DPe) are described. These belong to the following types: (1) The ionic brown compounds Y = Cl−, Br , ̄ I−, SCN−, CIO 4−, PF 6− and BPh 4−. (2) The polymeric red violet no-ionic green copounds [Au 6(DPE) 3]X 2. Conductivity measurements, infrared spectra and exchange reactions seem to indicate in these compounds the presence of gold custers of six atoms.
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