Abstract
The reaction of Os 3 (CO) 10 (μ-OMe)(μ-H) (1) with CH 2 (NMe 2 ) 2 has yielded the two isomeric cluster complexes Os 3 (CO) 9 [μ 3 -η 2 -C(H)NMe 2 ](μ-OMe)(μ-H) (2) and Os 3 (CO) 9 [C(H)NMe 2 ](μ-OMe)(μ-H) (3) which contain secondary (dimethylamino)carbene ligands. Compounds 2 and 3 were both characterized by IR, 1 H NMR, and single- analyses
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