Abstract
The title complex has been obtained from a reaction between Ru 3(CO) 10(PMe 2Ph) 2 and C 2(CO 2Me) 2. The alkyne is attached to the closed triangular Ru 3 cluster in the usual μ 3-η 2-|mode, the two Ru atoms to which the alkyne is σ-bonded also bearing the PMe 2Ph ligands, and being bridged by a CO group. A minor product also isolated from this reaction was partially characterised as Ru 3{C 2(CO 2Me) 2} 3(CO) 6-(PMe 2Ph) 2.
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